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The Interstellar Medium and Interstellar Molecules Ronald Maddalena National Radio Astronomy Observatory Interstellar Medium The Material Between the Stars Constituents: Gases: Dust Particles Hydrogen (92% by number) Helium (8%) Oxygen, Carbon, etc. (0.1%) 1% of the mass of the ISM Average Density: 1 H atom / cm3 7/17/2015 2 Interstellar Medium Properties State of H & C Temperature Densities (H/cm3) Percent Volume HII Regions & Planetary Nebulae H, C Ionized 5000 K 0.5 < 1% Diffuse ISM H, C Ionized 1,000,000 K 0.01 50% Diffuse Atomic H2 < 0.1 C Ionized 30-100 K 10-100 30% Diffuse Molecular 0.1 < H2 < 50% C+ > 50% 30-100 K 100-500 10% Translucent Molecular H2 ~ 1 C+ < 0.5, CO < 0.9 15-50 K 500-5000? Small Dense Molecular H2 ~ 1 CO > 0.9 10-50 K > 104 10% 7/17/2015 5 Interstellar Medium Properties 7/17/2015 6 Interstellar Medium – Life Cycle Planetary Nebula and HII Regions Non-Thermal Continuum Radiation Free-Free Emission Ionized regions (HII regions and planetary nebulae) Free electrons accelerated by encounters with free protons 7/17/2015 11 Spectral-Line Radiation Recombination Lines Discovered in 1965 by Hogburn and Mezger Ionized regions (HII regions and planetary nebulae) Free electrons temporarily recaptured by a proton Atomic transitions between outer orbital (e.g., N=177 to M = 176) 7/17/2015 15 1 1 3.3 10 2 2 m n 14 Spectral-Line Radiation Hyperfine transition of Hydrogen Discovered by Ewen and Purcell in 1951. Found in regions where H is atomic. Spin-flip (hyperfine) transition Electron & protons have “spin” In a H atoms, spins of proton and electron may be aligned or anti-aligned. Aligned state has more energy. Difference in Energy = h v v = 1420 MHz An aligned H atom will take 11 million years to flip the spin of the electron. But, 1067 atoms in Milky Way 1052 H atoms per second emit at 1420 MHz. Atomic Hydrogen Interstellar Molecules Hydroxyl (OH) first molecule found with radio telescopes (1964). Molecule Formation: Need high densities Lots of dust needed to protect molecules for stellar UV But, optically obscured – need radio telescopes Low temperatures (< 100 K) Some molecules (e.g., H2) form on dust grains Most form via ion-molecular gas-phase reactions 7/17/2015 Exothermic Charge transfer 18 Interstellar Molecules About 90% of the over 130 interstellar molecules discovered with radio telescopes. Rotational (electric dipole) Transitions Up to thirteen atoms Many carbon-based (organic) Many cannot exist in normal laboratories (e.g., OH) H2 most common molecule: No dipole moment so no radio transition. Only observable in UV (rotational) Astronomers use CO as a tracer for H2 7/17/2015 19 Molecular Clouds Discovered 1970 by Penzias, Jefferts, & Wilson and others. Coldest (5-30 K), densest (100 –106 H atoms/cm3) parts of the ISM. Where stars are formed 25-50% of the ISM mass A few percent of the Galaxy’s volume. Concentrated in spiral arms Dust Clouds = Molecular Clouds 7/17/2015 20 Discovery of Ethanol Molecules Discovered by the GBT 7/17/2015 24 Grain Chemistry Ion-molecular gas-phase reactions Ion-molecular gas-phase reactions Examples of types of reactions C+ + H2 → CH2+ + hν (Radiative Association) H2+ + H2 → H3+ + H (Dissociative Charge Transfer) H3+ + CO → HCO+ + H2 (Proton Transfer) H3+ + Mg → Mg+ + H2 + H (Charge Transfer) He+ + CO → He + C+ + O (Dissociative Charge Transfer) HCO+ + e → CO + H (Dissociative) C+ + e → C + hν (Radiative) Fe+ + grain → Fe + hν (Grain) 7/17/2015 27 Importance of H3+ Importance of H3+ -- Recent results First detected in 1994 in the infrared Creation: Destruction H3+ + e → H + H2 or 3H New laboratory measurements for reaction rates H2 + cr → H2+ + e H2 + H 2+ → H 3+ + H Dense Molecular clouds – expected and measured H3+ agree Diffuse Molecular clouds – measured H3+ is 100x higher than expected Cosmic ray ionization rate has to be higher in diffuse clouds than in dark clouds. Why? Confinement of cr in the diffuse molecular clouds Higher number of low energy cr than in current theory and which can’t penetrate dark clouds 7/17/2015 29 7/17/2015 30 Maser Emission 7/17/2015 31 Spectral-Line Radiation Milky Way Rotation and Mass? For any cloud For cloud B Observed velocity = difference between projected Sun’s motion and projected cloud motion. The highest observed velocity along the line of site VRotation = Vobserved + Vsun*sin(L) R = RSun * sin(L) Repeat for a different angle L and cloud B Determine VRotation(R) From Newton’s law, derive M(R) from V(R) Massive Supernovae 7/17/2015 34 Missing Mass 7/17/2015 35 Prebiotic Molecules The GBT and ALMA 7/17/2015 39 7/17/2015 40